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Alexander von Humboldt

Liquid‐Superrepellent Bioinspired Fibrillar Adhesives Alexander von Humboldt

Liquid‐Superrepellent Bioinspired Fibrillar Adhesives

Certain species of insects, arachnids, and reptiles, most notably the gecko lizards, have micro‐ or nanoscale fibril arrays on their footpads that function as high‐performance dry adhesives, allowing them to effortlessly climb on diverse surfaces. Such remarkable attachment ability is based on van der Waals and capillary forces, and the…
bubmag
April 2, 2020
Liquid‐Superrepellent Bioinspired Fibrillar Adhesives Alexander von Humboldt

Liquid‐Superrepellent Bioinspired Fibrillar Adhesives

Certain species of insects, arachnids, and reptiles, most notably the gecko lizards, have micro‐ or nanoscale fibril arrays on their footpads that function as high‐performance dry adhesives, allowing them to effortlessly climb on diverse surfaces. Such remarkable attachment ability is based on van der Waals and capillary forces, and the…
bubmag
April 2, 2020
Liquid‐Superrepellent Bioinspired Fibrillar Adhesives Alexander von Humboldt

Liquid‐Superrepellent Bioinspired Fibrillar Adhesives

Certain species of insects, arachnids, and reptiles, most notably the gecko lizards, have micro‐ or nanoscale fibril arrays on their footpads that function as high‐performance dry adhesives, allowing them to effortlessly climb on diverse surfaces. Such remarkable attachment ability is based on van der Waals and capillary forces, and the…
bubmag
April 2, 2020
A Janus‐type Heterogeneous Surfactant for Adipic Acid Synthesis Alexander von Humboldt

A Janus‐type Heterogeneous Surfactant for Adipic Acid Synthesis

Since adipic acid is one of the building blocks for the production of nylon‐6,6 by polycondensation with hexamethylene diamine, it is the industrially most important dicarboxylic acid.1 In commercial processes adipic acid is mainly synthesized by the nitric acid oxidation of a mixture of cyclohexanol and cyclohexanone (so‐called KA oil)…
bubmag
April 1, 2020
Triplet Energy Transfer from Ruthenium Complexes to Chiral Eniminium Ions: Enantioselective Synthesis of Cyclobutanecarbaldehydes by [2+2] Photocycloaddition Alexander von Humboldt

Triplet Energy Transfer from Ruthenium Complexes to Chiral Eniminium Ions: Enantioselective Synthesis of Cyclobutanecarbaldehydes by [2+2] Photocycloaddition

Introduction The electronic properties of olefins that are conjugated with a carbonyl group are altered by modifications at the carbonyl group. In this context, the formation of eniminium ions from α,β‐unsaturated aldehydes has had a major impact on the development of organocatalytic reactions.1 Kindled by the pioneering studies of MacMillan…
bubmag
April 1, 2020
Triplet Energy Transfer from Ruthenium Complexes to Chiral Eniminium Ions: Enantioselective Synthesis of Cyclobutanecarbaldehydes by [2+2] Photocycloaddition Alexander von Humboldt

Triplet Energy Transfer from Ruthenium Complexes to Chiral Eniminium Ions: Enantioselective Synthesis of Cyclobutanecarbaldehydes by [2+2] Photocycloaddition

Introduction The electronic properties of olefins that are conjugated with a carbonyl group are altered by modifications at the carbonyl group. In this context, the formation of eniminium ions from α,β‐unsaturated aldehydes has had a major impact on the development of organocatalytic reactions.1 Kindled by the pioneering studies of MacMillan…
bubmag
April 1, 2020
Remote Participation during Glycosylation Reactions of Galactose Building Blocks: Direct Evidence from Cryogenic Vibrational Spectroscopy Alexander von Humboldt

Remote Participation during Glycosylation Reactions of Galactose Building Blocks: Direct Evidence from Cryogenic Vibrational Spectroscopy

Prof. Dr. Mateusz Marianski Corresponding Author E-mail address: mmarians@hunter.cuny.edu http://orcid.org/0000-0002-6566-9931 Department of Chemistry and Biochemistry, Hunter College, 695 Park Ave, 10065 New York, NY, USA The Ph.D. Program in Chemistry, The Graduate Center of the City University of New York, 365 5th Ave, New York, NY, 10016 USASearch for more papers…
bubmag
April 1, 2020
A milestone in ultrafast gel fabrication from unconventional self-healing noble metal gels Alexander von Humboldt

A milestone in ultrafast gel fabrication from unconventional self-healing noble metal gels

Ultrafast Gel Fabrication. Credit: Ran DU et al. Matter 2020. Electrocatalysis is extensively involved in many important energy-related processes such as the oxygen reduction reaction (ORR) for fuel cells, the hydrogen evolution reaction (HER) for green hydrogen production, and the oxygen evolution reaction (OER) for metal-air batteries. Noble metal aerogels…
bubmag
March 23, 2020