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Alexander von Humboldt

Alexander von Humboldt

20 Smithsonian Shows to See in 2020

The new decade brings with it scores of new exhibitions at museums across the Smithsonian Institution in Washington, D.C. and in New York City. Many continue to mark the centenary of women’s suffrage; others expand views from other cultures and traditions. The 150th anniversary of professional baseball brings a couple…
bubmag
February 6, 2020
Alexander von Humboldt

Anharmonic Lattice Vibrations in Small‐Molecule Organic Semiconductors

Small‐molecule semiconducting crystals are studied extensively due to their potential for (opto)electronic applications such as light‐emitting diodes, field‐effect transistors, and solar cells.1-8 Linear oligoacenes are an archetypical family of such organic crystals that serve as an excellent testbed to study intrinsic properties of π‐conjugated solids. This is due to their…
bubmag
January 31, 2020
Alexander von Humboldt

Temperature‐Dependent Surface Enrichment Effects in Binary Mixtures of Fluorinated and Non‐Fluorinated Ionic Liquids

Introduction Ionic liquids (ILs) carrying fluorinated alkyl chains, in the following called fluorinated ILs, represent an interesting class of ILs because they often exhibit unique properties such as high thermal and chemical stability, and high gas solubility. Moreover, they commonly show low surface tension and/or are chemically and biologically inert.1…
bubmag
January 29, 2020
Alexander von Humboldt

An Adaptable N‐Heterocyclic Carbene Macrocycle Hosting Copper in Three Oxidation States

Introduction Copper complexes attract significant interest because of their various applications as catalysts in organic transformations such as C−C/X bond formation and C−H bond activation reactions, and also for their involvement in biological oxidation and oxygenation processes.1, 2 These copper‐mediated reactions generally exploit oxidation state changes of the metal ion,…
bubmag
January 24, 2020