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Alexander von Humboldt

Anharmonic Lattice Vibrations in Small‐Molecule Organic Semiconductors Alexander von Humboldt

Anharmonic Lattice Vibrations in Small‐Molecule Organic Semiconductors

Small‐molecule semiconducting crystals are studied extensively due to their potential for (opto)electronic applications such as light‐emitting diodes, field‐effect transistors, and solar cells.1-8 Linear oligoacenes are an archetypical family of such organic crystals that serve as an excellent testbed to study intrinsic properties of π‐conjugated solids. This is due to their…
bubmag
January 31, 2020
Advanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface‐Mounted Metal–Organic Frameworks Alexander von Humboldt

Advanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface‐Mounted Metal–Organic Frameworks

Introduction The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) play a crucial role in renewable energy provision schemes, which are relevant for e.g., metalair batteries, fuel cells and electrolyzers.1 Many efforts have been made to dev…
bubmag
January 29, 2020
Temperature‐Dependent Surface Enrichment Effects in Binary Mixtures of Fluorinated and Non‐Fluorinated Ionic Liquids Alexander von Humboldt

Temperature‐Dependent Surface Enrichment Effects in Binary Mixtures of Fluorinated and Non‐Fluorinated Ionic Liquids

Introduction Ionic liquids (ILs) carrying fluorinated alkyl chains, in the following called fluorinated ILs, represent an interesting class of ILs because they often exhibit unique properties such as high thermal and chemical stability, and high gas solubility. Moreover, they commonly show low surface tension and/or are chemically and biologically inert.1…
bubmag
January 29, 2020
Promoting the Electrocatalytic Performance of Noble Metal Aerogels by Ligand‐Directed Modulation Alexander von Humboldt

Promoting the Electrocatalytic Performance of Noble Metal Aerogels by Ligand‐Directed Modulation

Introduction Noble metals, which are chemically inert in their bulk form, manifest unusual activities when the size is reduced to the nanoscale. Therefore, many noblemetalbased nanostructures have been extensively studied in the last few decades for various …
bubmag
January 28, 2020
Barrierless Free Charge Generation in the High‐Performance PM6:Y6 Bulk Heterojunction Non‐Fullerene Solar Cell Alexander von Humboldt

Barrierless Free Charge Generation in the High‐Performance PM6:Y6 Bulk Heterojunction Non‐Fullerene Solar Cell

Organic solar cells (OSCs) have gained renewed interest with the emergence of nonfullerene acceptors (NFAs). Small molecule NFAs blended with donor polymers have rapidly advanced, reaching stateoftheart power conversion efficiencies above 16%1, 2 for single j…
bubmag
January 24, 2020
Barrierless Free Charge Generation in the High‐Performance PM6:Y6 Bulk Heterojunction Non‐Fullerene Solar Cell Alexander von Humboldt

Barrierless Free Charge Generation in the High‐Performance PM6:Y6 Bulk Heterojunction Non‐Fullerene Solar Cell

Organic solar cells (OSCs) have gained renewed interest with the emergence of nonfullerene acceptors (NFAs). Small molecule NFAs blended with donor polymers have rapidly advanced, reaching stateoftheart power conversion efficiencies above 16%1, 2 for single j…
bubmag
January 24, 2020
Barrierless Free Charge Generation in the High‐Performance PM6:Y6 Bulk Heterojunction Non‐Fullerene Solar Cell Alexander von Humboldt

Barrierless Free Charge Generation in the High‐Performance PM6:Y6 Bulk Heterojunction Non‐Fullerene Solar Cell

Organic solar cells (OSCs) have gained renewed interest with the emergence of nonfullerene acceptors (NFAs). Small molecule NFAs blended with donor polymers have rapidly advanced, reaching stateoftheart power conversion efficiencies above 16%1, 2 for single j…
bubmag
January 24, 2020
An Adaptable N‐Heterocyclic Carbene Macrocycle Hosting Copper in Three Oxidation States Alexander von Humboldt

An Adaptable N‐Heterocyclic Carbene Macrocycle Hosting Copper in Three Oxidation States

Introduction Copper complexes attract significant interest because of their various applications as catalysts in organic transformations such as C−C/X bond formation and C−H bond activation reactions, and also for their involvement in biological oxidation and oxygenation processes.1, 2 These copper‐mediated reactions generally exploit oxidation state changes of the metal ion,…
bubmag
January 24, 2020